Successfully complete the indicated task to unlock the corresponding character in Battle Coliseum mode:
- Ace: Win five Battle Royale matches and perform a Link Attack with any character.
- Brook: Win two matches with Sanji and a female teammate.
- Buggy: Successfully complete one Boss Rush and three Battle Royales with Luffy.
- Chopper: Reach Rank 1 in C League.
- Crocodile: Perform 15 dodges with Hancock and trigger five item word effects.
- Franky: Counter six times with Zoro.
- Hancock: Clear three Scrambles.
- Jimbei: Perform eight special attacks with Ace, 20 dodges with Ace, and two link attacks with Luffy and Ace.
- Nami: Win two Duel matches.
- Robin: Win two matches with Nami.
- Sanji: Get promoted to B League.
- Usopp: Reach Rank 1 in C League.
- Zoro: Get promoted to B League.